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Phenyl-substituted 1,4-benzoquinone diazides 2. Nitrogen coupling of 2,6-diphenyl-1,4-benzoquinone diazide with Β-dicarbonyl compounds

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A number of azo derivatives of 2,6-diphenyl-1,4-benzoquinone diazide have been prepared. In the crystalline state, these generally exist in the azophenol form. After prolonged standing in CDCl3 solution, they slowly isomerize to the hydrazo form, an equilibrium being established.

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Literature cited

  1. A. A. Efremenko, G. A. Nikiforov, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 2841 (1971).

  2. G. A. Nikiforov, K. de Jong, L. G. Plekhanova, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 2752 (1978).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 405–408, February, 1979.

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de Jong, K., Ershov, V.V., Nikiforov, G.A. et al. Phenyl-substituted 1,4-benzoquinone diazides 2. Nitrogen coupling of 2,6-diphenyl-1,4-benzoquinone diazide with Β-dicarbonyl compounds. Russ Chem Bull 28, 374–377 (1979). https://doi.org/10.1007/BF00925888

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  • DOI: https://doi.org/10.1007/BF00925888

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