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Fluorine-containing heterocumulenes 18. Fluoride-catalyzed reactions of hexafluoroacetone and perfluoroisobutylene with sulfinylamines

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The CsF-catalyzed reaction of hexafluoroacetone with sulfinylamines is a convenient method for synthesizing hexafluoroacetone imines.

  2. 2.

    Reaction of perfluoroisobutylene with sulfinylamines in the presence of CsF gives adducts of bis(trifluoromethyl)ketenimines with perfluoroisobutylene.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    Yu. V. Zeifman, E. G. Ter-Gabrielyan, D. P. Del'tsova & N. P. Gambaryan

Authors
  1. Yu. V. Zeifman
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  2. E. G. Ter-Gabrielyan
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  3. D. P. Del'tsova
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  4. N. P. Gambaryan
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Additional information

See [1] for communication 17.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 396–398, February, 1979.

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Zeifman, Y.V., Ter-Gabrielyan, E.G., Del'tsova, D.P. et al. Fluorine-containing heterocumulenes 18. Fluoride-catalyzed reactions of hexafluoroacetone and perfluoroisobutylene with sulfinylamines. Russ Chem Bull 28, 366–368 (1979). https://doi.org/10.1007/BF00925885

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  • DOI: https://doi.org/10.1007/BF00925885

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