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A study of the electrochemical reduction of certain arylazo compounds, and the behavior of the resulting anion-radicals, by ESR and polarographic methods

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the electrochemical reduction of diazo compounds in aprotic media, and of chemical reactions accompanied by transfer of an electron to a molecule.

  2. 2.

    The formation of primary and secondary anion-radicals has been demonstrated, the structures of these radicals were determined, and a study was made of the delocalization of the unpaired electron.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    A. V. Il'yasov, A. A. Vafina, V. I. Morozov, R. M. Zaripova, V. N. Gruzdneva & L. A. Kazitsyna

  2. M. V. Lomonosov Moscow State University, USSR

    A. V. Il'yasov, A. A. Vafina, V. I. Morozov, R. M. Zaripova, V. N. Gruzdneva & L. A. Kazitsyna

Authors
  1. A. V. Il'yasov
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  2. A. A. Vafina
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  3. V. I. Morozov
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  4. R. M. Zaripova
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  5. V. N. Gruzdneva
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  6. L. A. Kazitsyna
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 338–342, February, 1979.

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Il'yasov, A.V., Vafina, A.A., Morozov, V.I. et al. A study of the electrochemical reduction of certain arylazo compounds, and the behavior of the resulting anion-radicals, by ESR and polarographic methods. Russ Chem Bull 28, 311–315 (1979). https://doi.org/10.1007/BF00925874

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  • DOI: https://doi.org/10.1007/BF00925874

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