Conclusions
It is suggested that the physical and chemical behavior of the aryllithium compounds results from the low value of the singlet-triplet state separation δEST since this entails that a considerable proportion of the molecules be in the lower excited triplet state.
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Literature cited
G. Fraenkel, D. C. Adams, and R. R. Dean, J. Phys. Chem.,72, 944 (1968).
A. J. Jones, D. M. Grant, J. G. Russel, and G. Fraenkel, J. Phys. Chem.,73, 1624 (1969).
R. W. Hoffmann, Dehydrobenzene and Cycloalkynes, Academic Press, New York-London (1967), p. 43.
J. A. Pople, D. L. Beveridge, and P. A. Dobosh, J. Chem. Phys.,47, 2026 (1967).
J. A. Pople and R. K. Nesbet, J. Chem. PHys.,22, 571 (1954).
T. L. Brown, Adv. Organomet. Chem.,3, 365 (1965).
M. H. Palmer and S. M. F. Kennedy, J. Chem. Soc. Perkin Trans. 2,1976, 81.
A. I. D'yachenko, A. I. Ioffe, and O. M. Nefedov, Izv. Akad. Nauk SSSR, Ser. Khim., 366 (1979).
A. Carrington and A. D. McLachlan, Introduction to Magnetic Resonance with Applications to Chemistry and Chemical Physics, Harper-Row (1967).
A. I. D'yachenko, Dissertation, Moscow (1973).
E. E. Zaev, Yu. N. Molin, G. M. Zhidomirov, and V. V. Voevodskii, Dokl. Akad. Nauk SSSR,173, 1370 (1967).
A. N. Rodionov, D. N. Shigorin, T. V. Talalaeva, G. V. Tsareva, and K. A. Kocheshkov, Zh. Fiz. Khim.,40, 2265 (1966).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 307–310, February, 1979.
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Abronin, I.A., Shteinshneider, A.Y., Zhidomirov, G.M. et al. Effect of low-lying excited triplet states on the physical and chemical properties of aryllithium compounds. Russ Chem Bull 28, 281–284 (1979). https://doi.org/10.1007/BF00925867
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DOI: https://doi.org/10.1007/BF00925867