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The kinetics and mechanism of the reaction of ozone with phenol in aqueous solution

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Ozone reacts with phenol in aqueous solution, attacking the phenol group and opening the aromatic ring.

  2. 2.

    The reaction follows a bimolecular rate law over the entire range of ozone and phenol concentrations.

  3. 3.

    The Arrhenius parameters for reaction in water are anomalously high in comparison with the parameters for this same reaction in nonaqueous solution.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    S. D. Razumovskii, V. S. Ovechkin & M. L. Konstantinova

Authors
  1. S. D. Razumovskii
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  2. V. S. Ovechkin
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  3. M. L. Konstantinova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 285–288, February, 1979.

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Razumovskii, S.D., Ovechkin, V.S. & Konstantinova, M.L. The kinetics and mechanism of the reaction of ozone with phenol in aqueous solution. Russ Chem Bull 28, 261–264 (1979). https://doi.org/10.1007/BF00925862

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  • DOI: https://doi.org/10.1007/BF00925862

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