Skip to main content
SpringerLink
Log in

Extralattice anions and brØnsted acid centers of rare-earth zeolites of the faujasite group

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    On the basis of spectroscopic data the authors have refined the interpretation of the hydroxyl bands in the IR spectra of zeolites of the faujasite group with rare-earth cations.

  2. 2.

    In zeolites of type X, dehydrated in vacuum, the charges of the acid hydroxyl groups are compensated by the charges on the OH− and O2− anions. In zeolites of type Y, dehydrated in the same conditions, there are no O2− ions.

  3. 3.

    The authors suggest a probable mechanism for the influence of water coordinated by cations on the frequency of the acid hydroxyl groups.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. J. A. Rabo, C. L. Angell, and V. Shoemaker, Principles of Prediction of Catalytic Action [Russian translation], Vol. 2, Nauka (1970), p. 115.

  2. J. W. Ward, J. Catal.,13, 321 (1969).

    Google Scholar 

  3. J. M. Bennett, J. V. Smith, and C. L. Angell, Mater. Res. Bull,4, 77 (1969).

    Google Scholar 

  4. Y. I. Ryskin, S. P. Zhdanov, G. P. Stavitskaya, and S. V. Pogarev, Izv. Akad. Nauk SSSR, Ser. Neorg. Mater.,9, 1012 (1973).

    Google Scholar 

  5. P. A. Jacobs and J. B. Uytterhoeven, J. Chem. Soc. Faraday Trans.,1, 69, 373 (1973).

    Google Scholar 

  6. G. P. Stavitskaya, Ya. I. Ryskin, and S. P. Zhdanov, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 33.

  7. L. A. Ignat'eva, L. V. Efimenko, S. A. Slivko, L. P. Brivnina, and L. I. Piguzova, Zh. Prikl. Spektrosk.,20, 231 (1974).

    Google Scholar 

  8. D. H. Olson, G. T. Kokotailo, and J. F. Charnell, J. Colloid Interface Sci.,28, 305 (1968).

    Google Scholar 

  9. Ya. I. Ryskin and G. P. Stavitskaya, The Hydrogen Bond and the Structure of Hydrosilicates [in Russian], Nauka, Leningrad (1972).

    Google Scholar 

  10. P. E. Eberly and C. N. Kimberlin, Mol. Sieve Zeolites — II: Advances in Chemistry Series 102, Amer. Chem. Soc., Washington (1971), p. 374.

    Google Scholar 

  11. V. G. Gvakhariya, Dissertation, Tbilisi (1975).

  12. R. L. Stevenson, J. Catal.,21, 113 (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Academy of Sciences of the USSR, Leningrad

    G. P. Stavitskaya, Ya. I. Ryskin & S. P. Zhdanov

Authors
  1. G. P. Stavitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ya. I. Ryskin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. P. Zhdanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 272–280, February, 1979.

The authors thank N. N. Samulevich for lending the Na forms of the zeolites, synthesized by him.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stavitskaya, G.P., Ryskin, Y.I. & Zhdanov, S.P. Extralattice anions and brØnsted acid centers of rare-earth zeolites of the faujasite group. Russ Chem Bull 28, 250–256 (1979). https://doi.org/10.1007/BF00925860

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00925860

Keywords

Search

Navigation