Conclusions
-
1.
The authors have synthesized for all the rare earths the hitherto undescribed solid mono-Β-hydroxyethyliminodiacetates of the composition LnZCl·4H2O.
-
2.
They have subjected the LnZCl·4H2O to x-ray, thermogravimetric, and derivatographic analysis. They have investigated the IR spectra of the hydrates and anhydrous LnZCl, and their deuteroderivatives.
-
3.
From the data obtained, they infer that LnZCl·4H2O are polymeric, and they also draw certain conclusions on the character of the bond of the Ln3+ ion with different donor groups of the ligand in these compounds.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
L. C. Tompson and I. A. Loraas, Inorg. Chem.,2, 594 (1963).
N. M. Dyatlova, V. Ya. Temkina, Yu. F. Belugin, O. Yu. Lavrova, L. é. Bertina, V. D. Iozefovich, N. N. Kalmykova, and E. P. Zhirov, Zh. Neorg. Khim.,10, 1131 (1965).
é. D. Romanenko, L. V. Novikova, and N. A. Kostromina, Zh. Neorg. Khim.,19, 1554 (1974).
N. D. Mitrofanova, é. D. Filippova, B. M. Fedorov, and L. I. Martynenko, Zh. Neorg. Khim.,22, 1235 (1977).
L. Wolf, Osterreich. Chem. Z.,60, No. 4, 99 (1959).
V. P. Khramov and G. A. Aliev,17, 1845 (1972).
V. P. Khramov, V. G. Egorova, and A. L. Bogacheva, Zh. Neorg. Khim.,20, 890 (1975).
N. M. Prutkova, L. I. Martynenko, A. I. Grigor'ev, and N. D. Mitrofanova, Zh. Neorg. Khim.,11, 1277 (1966).
A. I. Grigor'ev, N. D. Mitrofanova, and L. I. Martynenko, Zh. Neorg. Khim.,10, 1409 (1965).
L. I. Martynenko, N. I. Pechurova, A. I. Grigor'ev, and V. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 1236 (1970).
é. D. Filippova, N. D. Mitrofanova, L. I. Martynenko, and V. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 1706 (1974).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley (1963).
L. J. Bellamy, Infrared Spectra of Complex Molecules, 2nd edition, Wiley, New York (1958).
I. N. Polyakova, T. K. Senina, T. N. Polynova, M. A. Porai-Koshits, and N. D. Mitrofanova, Zh. Strukt. Khim.,18, 1128 (1977).
K. M. Belyaeva, M. A. Porai-Koshits, N. D. Mitrofanova, and L. I. Martynenko, Zh. Strukt. Khim.,7, 130 (1966).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 263–267, February, 1979.
Rights and permissions
About this article
Cite this article
Mitrofanova, N.D., Filippova, E.D., Martynenko, L.I. et al. Preparation and properties of solid rare-earth Β-hydroxyethyliminodiacetates. Russ Chem Bull 28, 241–245 (1979). https://doi.org/10.1007/BF00925858
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00925858