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Reactions of olefin oxides and thiiranes with dialkylisothiocyanatoarsines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the reactions of dialkylisothiocyanatoarsines withα-oxides and thiiranes. A mechanism was proposed for the formation of the 2-thiocyanatoalkyl esters of arsinous (thioarsinous) acids.

  2. 2.

    Some characteristics of the exchange reactions of the 2-thiocyanatoalkyl esters of arsinous and thioarsinous acids with acyl halides and phosphoryl halides were established.

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Literature cited

  1. A. F. Kolomiets, G. S. Levskaya, and N. K. Bliznyuk, USSR Patent 210,154 (1956); Byull. Izobr., No. 6, 24 (1968).

  2. A. F. Kolomiets, G. S. Levskaya, and N. K. Bliznyuk, USSR Patent 192,809 (1966); Byull. Izobr., No. 6, 26 (1967).

  3. British Patent 923,582 (1963); C. A.,60, 3011 (1964).

  4. A. V. Fokin, A. F. Kolomiets, Yu. N. Studnev, A. I. Rapkin, and V. I. Yakutin, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 1406.

  5. N. A. Razumova, A. A. Petrov, and Zh. L. Evtikhov, Zh. Obshch. Khim.,38, 2542 (1967).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 406–410, February, 1975.

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Fokin, A.V., Kolomiets, A.F. & Levskaya, G.S. Reactions of olefin oxides and thiiranes with dialkylisothiocyanatoarsines. Russ Chem Bull 24, 334–338 (1975). https://doi.org/10.1007/BF00925781

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  • DOI: https://doi.org/10.1007/BF00925781

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