Conclusions
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1
On the example of the carboranyl derivatives of mercury it was shown that the essence of nucleophilic catalysis in reactions of the SE1-N type consists in the one-electron reduction of the metal-carbon bond with the formation of the carbanion.
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2.
Under anionic catalysis conditions organomercury compounds, which contain strong electron-acceptor substituents, are capable of exchange and addition reactions that outwardly resemble the analogous transformations of organomagnesium and organolithium compounds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 395–398, February, 1975.
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Bregadze, V.I., Sadzhaya, D.N. & Okhlobystin, O.Y. Nature of nucleophilic coaction during electrophilic substitution on example of reactions of organomercury derivatives of carboranes. Russ Chem Bull 24, 323–325 (1975). https://doi.org/10.1007/BF00925778
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DOI: https://doi.org/10.1007/BF00925778