Skip to main content
SpringerLink
Log in

Carbonylation reactions

Communication 19. Activity of salts of Group II metals of periodic system in carbonylation of amines with carbon monoxide

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The salts of the Group II metals cause the carbonylation of piperidine and diethylamine at 200–250° and a CO pressure of 50–200 atm predominantly to the corresponding formyl derivative in up to 82% yield when based on amine taken for reaction.

  2. 2.

    The chlorides are the most effective, the activity of which decreases in the order: CaCl2 > SrCl2 > MgCl2 > BaCl2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. Ya. Yu. Aliev, Carbonylation of Organic Compounds [in Russian], Nauka, Tashkent (1964).

    Google Scholar 

  2. W. Reppe and A. Magin, British Patent 672,376 (1952); C. A.,47, 5428 (1953).

    Google Scholar 

  3. B. K. Nefedov, V. A. Petukhov, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2535.

  4. A. A. Grinberg, Introduction to the Chemistry of Complexes [in Russian], Khimiya, Leningrad (1971).

    Google Scholar 

  5. A. A. Slinkin, B. K. Nefedov, A. V. Kucherov, M. I. Loktev, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 2163.

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. K. Nefedov, N. S. Sergeeva & Ya. T. Éidus

Authors
  1. B. K. Nefedov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. S. Sergeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ya. T. Éidus
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 360–363, February, 1975.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nefedov, B.K., Sergeeva, N.S. & Éidus, Y.T. Carbonylation reactions. Russ Chem Bull 24, 292–295 (1975). https://doi.org/10.1007/BF00925771

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00925771

Keywords

Search

Navigation