Conclusions
Alkenyldichlorophosphines are formed in high yields when alkenes are phosphorylated by treatment with PCl5 in the presence of hydrosilanes under conditions that promote the formation of trimolecular complexes of alkene, PCl5, and hydrosilane.
Literature cited
A. F. Kolomiets, A. V. Fokin, L. S. Rudnitskaya, and A. A. Krolevets, Izv. Akad. Nauk SSSR, Ser. Khim., 181 (1976).
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.207–209, January, 1976.
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Kolomiets, A.F., Fokin, A.V., Krolevets, A.A. et al. Reactions of alkenes with phosphorus pentachloride and trichlorosilane. Russ Chem Bull 25, 200–201 (1976). https://doi.org/10.1007/BF00925655
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DOI: https://doi.org/10.1007/BF00925655