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Conclusions

  1. 1.

    Bis(phenyldimethylsilyl)mercury was synthesized, the reactions of which with molecular oxygen, benzoyl peroxide, 1,2-dibromoethane, HgCl2, and acetic acid proceed with cleavage of the Si-Hg-Si fragment.

  2. 2.

    A study was made of the photodecomposition reactions of bis(phenyldimethylsilyl)mercury in either benzene or cyclohexane medium at 40 and 80°, and also its thermal decomposition in cyclohexane at 200°.

  3. 3.

    The photoreaction of bis(phenyldimethylsilyl)mercury in triethylgermane solution gives mercury, phenyldimethylsilane, and hexaethyldigermane.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.204–207, January, 1976.

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Gladyshev, E.N., Yuntila, L.O., Razuvaev, G.A. et al. Bis (phenyldimethylsilyl)mercury. Russ Chem Bull 25, 197–199 (1976). https://doi.org/10.1007/BF00925654

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  • DOI: https://doi.org/10.1007/BF00925654

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