Skip to main content
SpringerLink
Log in

Proton transfer from 3, 6-di-tert-butyl-2-hydroxyphenoxyl to tertiary amines

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of reversible proton transfer from 3,6-di-tert-butyl-2-hydroxyphenoxyl to tertiary aliphatic amines and 4-methylpyridine; the equilibrium constants and rate constants of proton transfer from radical to amine were obtained.

  2. 2.

    The obtained thermodynamic and kinetic parameters are discussed from the standpoint of the aggregation of the ion pairs of the semiquinone radical ions into polymeric associates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. A. I. Prokof'ev, N. M. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 2213 (1974).

  2. A. Carrington and A. McLachlan, Introduction to Magnetic Resonance with Applications to Chemistry and Chemical Physics, Harper and Row (1967).

  3. A. I. Prokof'ev, A. S. Masalimov, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 193 (1976).

  4. H. Becker, Introduction to Electronic Theory of Organic Reactions [Russian translation], Mir (1965).

  5. I. S. Belostotskaya, N. L. Komissarova, É. V. Dzhuaryan, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser, Khim., 1594 (1972).

  6. N. L. Komissarova, I. S. Belostotskaya, É. V. Dzhuaryan, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1380 (1973).

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. S. Masalimov, A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov & M. I. Kabachnik

Authors
  1. A. S. Masalimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Prokof'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Bubnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. P. Solodovnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. I. Kabachnik
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.190–193, January, 1976.

The authors express their gratitude to I. S. Belostotskaya and V. V. Ershov for supplying the 3, 6-di-tert-butyl-o-quinone [5,6].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Masalimov, A.S., Prokof'ev, A.I., Bubnov, N.N. et al. Proton transfer from 3, 6-di-tert-butyl-2-hydroxyphenoxyl to tertiary amines. Russ Chem Bull 25, 181–183 (1976). https://doi.org/10.1007/BF00925649

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00925649

Keywords

Search

Navigation