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Charge-transfer complexes of aroxymethyltriethylsilanes

  • N. I. Golovanova
  • N. I. Shergina
  • N. F. Chernov
  • M. G. Voronkov
Brief Communications

Conclusions

  1. 1.

    The complexing of aroxymethyltriethylsilanes with tetracyanoethylene was studied spectrophotometrically. The same relation between the ionization potentials (ID) and theνmax of the charge-transfer bands for p-XC6H4OCH3 and p-XC6H4OCH2Si(C2H5)3, and also for various classes of aromatic compounds, shows that the investigated molecules are π donors.

     
  2. 2.

    A decrease in the ID of the studied compounds Indicates that their π-donor capacity is greater than that of the corresponding anisoles.

     

Keywords

Aromatic Compound Ionization Potential Anisole Tetracyanoethylene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • N. I. Golovanova
    • 1
  • N. I. Shergina
    • 1
  • N. F. Chernov
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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