Charge-transfer complexes of aroxymethyltriethylsilanes

  • N. I. Golovanova
  • N. I. Shergina
  • N. F. Chernov
  • M. G. Voronkov
Brief Communications


  1. 1.

    The complexing of aroxymethyltriethylsilanes with tetracyanoethylene was studied spectrophotometrically. The same relation between the ionization potentials (ID) and theνmax of the charge-transfer bands for p-XC6H4OCH3 and p-XC6H4OCH2Si(C2H5)3, and also for various classes of aromatic compounds, shows that the investigated molecules are π donors.

  2. 2.

    A decrease in the ID of the studied compounds Indicates that their π-donor capacity is greater than that of the corresponding anisoles.



Aromatic Compound Ionization Potential Anisole Tetracyanoethylene 
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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • N. I. Golovanova
    • 1
  • N. I. Shergina
    • 1
  • N. F. Chernov
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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