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Semicoordination complexes of rhenium carbonyl

4. Reaction of carboxylic acid chlorides and nitrosyl chloride with the complex [CpRe(CO)2X]MgX

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of [CpReI(CO)2]MgI (I) with carboxylic acid chlorides RCOCl (R=CH3, C6H5) gave the rhenium semicoordination complexes CpReI(CO)2COCH3 (II) and CpReI(CO)2COC6H5 (IV).

  2. 2.

    The decarbonylation of (II) gave CpReI(CO)2CH3 (III).

  3. 3.

    The reaction of (I) with nitrosyl chloride gave the nitrosyl complex CpReBr(CO)NO (V).

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Literature cited

  1. A. N. Nesmeyanov, N. E. Kolobova, Yu. V. Makarov, and K. N. Anisimov, Zh. Obshch. Khim.,44, 2222 (1974).

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  2. A. N. Nesmeyanov, N. E. Kolobova, Yu. V. Makarov, and K. N. Anisimov, Izv. Akad. Nauk SSSR, Ser. Khim., 1826 (1969).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. N. Nesmeyanov, N. E. Kolobova, Yu. V. Makarov, E. I. Kazimirchuk & K. N. Anisimov

Authors
  1. A. N. Nesmeyanov
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  2. N. E. Kolobova
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  3. Yu. V. Makarov
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  4. E. I. Kazimirchuk
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  5. K. N. Anisimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.159–161, January, 1976.

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Nesmeyanov, A.N., Kolobova, N.E., Makarov, Y.V. et al. Semicoordination complexes of rhenium carbonyl. Russ Chem Bull 25, 147–149 (1976). https://doi.org/10.1007/BF00925638

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  • DOI: https://doi.org/10.1007/BF00925638

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