Conclusions
-
1.
A study was made of the ability of CpTiX3, where X=F, Cl, Br, I, Cp=C5H5, to form molecular complexes with some n-donors.
-
2.
The compounds C5H5TiBr3·THF, C5(CH3)5TiBr3·THF, and C5H5TiI3·2THF were obtained.
Similar content being viewed by others
Literature cited
G. K. Semin, O. V. Nogina, V. A. Dubovitskii, T. A. Babushkina, E. V. Bryukhova, and A. N. Nesmeyanov, Dokl. Akad. Nauk SSSR,194, 101 (1970).
A. Anagnostopoulos and D. Nicholls, J. Inorg. Nucl. Chem.,28, 3045 (1966).
A. S. Nesmeyanov, O. V. Nogina, V. A. Dubovitskii, B. A. Kvasov, P. V. Petrovskii, and N. A. Lazareva, Izv. Akad. Nauk SSSR, Ser. Khim., 2729 (1971).
H. S. Ahuja, S. C. Jain, and R. Rivest, J. Inorg. Nucl. Chem.,30, 2459 (1968).
E. N. Gur'yanova, I. P. Gol'dshtein, and I. P. Romm, The Donor-Acceptor Bond [in Russian], Khimiya (1973), p.130.
G. W. A. Fowles, D. A. Rice, and J. D. Wilkins, J. Chem. Soc., 1920 (1971).
H. C. Beachell and S. A. Butter, Inorg. Chem.,4, 113 (1965).
P. M. Druce, B. M. Kingston, M. F. Lapport, T. R. Spalding, and R. C. Srivastava, J. Chem. Soc.,A1969, 2106.
A. N. Nesmeyanov, O. V. Nogina, E. I. Fedin, V. A. Dubovitskii, B. A. Kvasov, and P. V. Petrovskii, Dokl. Akad. Nauk SSSR,205, 857 (1972).
C. L. Sloan and W. Barber, Chim. Ind. (Milan),42, 877 (1960); A. F. Reid and P. C. Wailes, J. Organometal. Chem.,2, 329 (1964); A. N. Nesmeyanov, O. V. Nogina, B. V. Lokshm, and V. A. Dubovitskii, Doki. Akad. Nauk SSSR,182, 844 (1968).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.148–150, January, 1976.
The authors express their gratitude to B. V. Lokshin, E. I. Fedin, and P. V. Petrovskii for taking the spectra and their help in interpreting them.
Rights and permissions
About this article
Cite this article
Nogina, O.V., Uralets, I.A., Drogunova, G.I. et al. Molecular compounds of cyclopentadienyltitanium trihalides with tetrahydrofuran. Russ Chem Bull 25, 135–137 (1976). https://doi.org/10.1007/BF00925635
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00925635