Conclusions
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1.
Previously unknown acetylenicγ-hydroxy aldehydes were obtained by oxidation of primarytertiary acetylenicγ-glycols with neutral manganese dioxide.
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2.
The addition of n-butylamine to acetylenicγ -hydroxy aldehydes takes place at the carbonyl group to form acetylenic azomethines.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.121–124, January, 1976.
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Medvedeva, A.S., Safronova, L.P., Chichkareva, G.G. et al. Synthesis of acetylenic γ -hydroxy aldehydes and their reaction with primary amines. Russ Chem Bull 25, 107–110 (1976). https://doi.org/10.1007/BF00925629
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DOI: https://doi.org/10.1007/BF00925629