Skip to main content
SpringerLink
Log in

Catalytic properties of the calcium forms of dealuminized type Y zeolites during the alkylation of benzene with ethylene

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An increase in the SiO2/Al2O3 ratio (x) in type Y zeolites through dealuminization with ethylenediaminetetraacetic acid leads to an increase in their catalytic activity during the alkylation of benzene with ethylene.

  2. 2.

    The properties of CaNaY zeolites of the same composition prepared from NaY obtained by hydrothermal synthesis and by dealuminization of samples with a small value of x are identical.

  3. 3.

    Carbon dioxide exerts an accelerating effect on the Ca forms of dealuminized type Y zeolites of various compositions and has no effect on the properties of NaY'.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. J. A. Rabo, M. L. Poutsma, and G. W. Skeels, Proc. Fifth Inter. Congr. Catal., Miami Beach,2, 1353 (1973).

    Google Scholar 

  2. G. T. Kerr, J. Phys. Chem.,72, 2594 (1968).

    Google Scholar 

  3. L. I. Piguzova, M. M. Dubinin, E. N. Prokof'eva, G. M. Plavnik, G. M. Fedorova, and A. S. Vitukhina, Izv. Akad. Nauk SSSR, Ser. Khim., 1204 (1970).

  4. D. Barthomeuf and R. Beaumont, C. R. Acad. Sci.,C269, 1345 (1969).

    Google Scholar 

  5. R. Beaumont and D. Barthomeuf, C. R. Acad. Sci.,C272, 363 (1971).

    Google Scholar 

  6. Baik-Hyon Ha, D. Barthomeuf, and Y. Trambouze, C. R. Acad. Sci.,C274, 1017 (1972).

    Google Scholar 

  7. K. Y. Topchieva and Huo Shih T'huoang, Kinet. Katal.,11, 490 (1970).

    Google Scholar 

  8. K. V. Topchieva, Huo Shih T'huoang, and B. G. Falyazi, Vestn. Mosk., Un-ta, Ser. Khim.,14, 282 (1973).

    Google Scholar 

  9. K. V. Topchieva and Huo Shih T'huoang, Kinet. Katal.,14, 1491 (1973).

    Google Scholar 

  10. K. V. Topchieva, Huo Shih T'huoang, and A. P. Monyakin, Vestn. Mosk. Un-ta, Ser. Khim.,14, 282 (1973).

    Google Scholar 

  11. G. T. Kerr, Advances Chem. Ser., No.121, 219 (1973).

    Google Scholar 

  12. D. Barthomeuf and R. Beaumont, J. Catal.,30, 288 (1973).

    Google Scholar 

  13. K. Tsutsumi, H. Kajiwara, H. K. Koh, and H. Takahashi, Proc. Third Inter Conf. on Molecular Sieves, Zurich, 358 (1973).

  14. Kh. M. Minachev and Ya. I. Isakov, Dokl. Akad. Nauk SSSR,202, 1341 (1972).

    Google Scholar 

  15. Ya. I. Isakov, Kh. M. Minachev, and V. P. Kalinin, Izv. Akad. Nauk SSSR, Ser. Khim., 1138 (1973).

  16. Author's Certificate of the USSR No. 410004 (1973); Byul. Izobr., No.1, 79 (1974).

  17. Ya. I. Isakov, Kh. M. Minachev, and N. Ya. Usachev, Izv. Akad. Nauk SSSR, Ser. Khim., 1588 (1973).

  18. Kh. M. Minachev and Ya. I. Isakov, Izv. Akad. Nauk SSSR, Ser. Khim., 767 (1974).

  19. Kh. M. Minachev, R. V. Dmitriev, Ya. I. Isakov, and O. D. Bronnikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2689 (1973).

  20. R. Beaumont and D. Barthomeuf, J. Catal.,27, 45 (1972).

    Google Scholar 

  21. E. Dempsey, J. Catal.,33, 497 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Kh. M. Minachev, Ya. I. Isakov & Yu. S. Akhmetov

Authors
  1. Kh. M. Minachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ya. I. Isakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. S. Akhmetov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 108–112, January, 1976.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Minachev, K.M., Isakov, Y.I. & Akhmetov, Y.S. Catalytic properties of the calcium forms of dealuminized type Y zeolites during the alkylation of benzene with ethylene. Russ Chem Bull 25, 94–98 (1976). https://doi.org/10.1007/BF00925626

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00925626

Keywords

Search

Navigation