Conclusions
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1.
Molecules of arylvinyl selenides have a maximally conjugated planar s-trans structure,
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2.
The conformations of arylvinyl sulfides are determined by the ratio of the energies of conjugation and steric repulsion of atoms; the disturbance of coplanarity occurs on account of rotation of the aryl radicals.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp. 99–103, January, 1976.
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Vul'fson, S.G., Teitel'baum, A.B., Mannafov, T.G. et al. Anisotropy of the polarizability and steric structure of arylvinyl selenides and arylvinyl sulfides. Russ Chem Bull 25, 86–89 (1976). https://doi.org/10.1007/BF00925624
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DOI: https://doi.org/10.1007/BF00925624