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Anisotropy of the polarizability and steric structure of arylmethanesulfonates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The components of the tensor of polarizability of the S- O bond in methylmethanesulfonate were determined.

  2. 2.

    Arylmethanesulfonate exists in a conformation with a gauche arrangement of the methyl and aryl radicals.

  3. 3.

    The aryl radicals in the molecules of arylmethanesulfonates project out of the plane of C-O-S by 40–45° in the direction of the oxygen atom of the sulfo group.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, S. G. Vul'fson, G. G. Butenko, O. A. Samarina & A. N. Vereshchagin

Authors
  1. B. A. Arbuzov
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  2. S. G. Vul'fson
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  3. G. G. Butenko
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  4. O. A. Samarina
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  5. A. N. Vereshchagin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.94–98, January, 1976.

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Arbuzov, B.A., Vul'fson, S.G., Butenko, G.G. et al. Anisotropy of the polarizability and steric structure of arylmethanesulfonates. Russ Chem Bull 25, 82–85 (1976). https://doi.org/10.1007/BF00925623

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  • DOI: https://doi.org/10.1007/BF00925623

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