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Chemical polarization of nuclei

Communication 2. CPN-31p in the reaction of hydroperoxides with phosphites, catalyzed by vanadyl acetylacetonate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the reaction of hydroperoxides with phosphites, catalyzed by vanadyl acetylacetonate, chemical polarization of31P nuclei (CPN) is suppressed or greatly weakened.

  2. 2.

    The results of CPN-31P in the presence of a catalyst confirm the occurrence of the reaction of hydroperoxide with phosphites according to two pathways — radical and nonradical. The reaction of hydroperoxide with phosphites catalyzed by vanadyl acetylacetonate proceeds according to a nonradical mechanism.

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Literature cited

  1. A. D. Pershin, D. G. Pobedimskii, V. A. Kurbatov, and A. L. Buchachenko, Izv. Akad. Nauk SSSR, Ser. Khim., 581 (1975).

  2. D. G. Pobedimskii, E. G. Chebotareva, Sh. A. Nasybullin, P. A. Kirpichnikov, and A. L. Buchachenko, Dokl. Akad. Nauk SSSR,220, 641 (1975).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    D. G. Pobedimskii, A. D. Pershin, Sh. A. Nasybullin & A. L. Buchachenko

  2. S. M. Kirov Kazan' Chemicotechnological Institute, USSR

    D. G. Pobedimskii, A. D. Pershin, Sh. A. Nasybullin & A. L. Buchachenko

Authors
  1. D. G. Pobedimskii
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  2. A. D. Pershin
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  3. Sh. A. Nasybullin
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  4. A. L. Buchachenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp.79–81, January, 1976.

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Pobedimskii, D.G., Pershin, A.D., Nasybullin, S.A. et al. Chemical polarization of nuclei. Russ Chem Bull 25, 68–70 (1976). https://doi.org/10.1007/BF00925620

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  • DOI: https://doi.org/10.1007/BF00925620

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