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Chemical polarization of nuclei

Communication 2. CPN-31p in the reaction of hydroperoxides with phosphites, catalyzed by vanadyl acetylacetonate
  • D. G. Pobedimskii
  • A. D. Pershin
  • Sh. A. Nasybullin
  • A. L. Buchachenko
Physical Chemistry

Conclusions

  1. 1.

    In the reaction of hydroperoxides with phosphites, catalyzed by vanadyl acetylacetonate, chemical polarization of31P nuclei (CPN) is suppressed or greatly weakened.

     
  2. 2.

    The results of CPN-31P in the presence of a catalyst confirm the occurrence of the reaction of hydroperoxide with phosphites according to two pathways — radical and nonradical. The reaction of hydroperoxide with phosphites catalyzed by vanadyl acetylacetonate proceeds according to a nonradical mechanism.

     

Keywords

Hydroperoxide Acetylacetonate Phosphite Chemical Polarization Vanadyl Acetylacetonate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. D. Pershin, D. G. Pobedimskii, V. A. Kurbatov, and A. L. Buchachenko, Izv. Akad. Nauk SSSR, Ser. Khim., 581 (1975).Google Scholar
  2. 2.
    D. G. Pobedimskii, E. G. Chebotareva, Sh. A. Nasybullin, P. A. Kirpichnikov, and A. L. Buchachenko, Dokl. Akad. Nauk SSSR,220, 641 (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • D. G. Pobedimskii
    • 1
    • 2
  • A. D. Pershin
    • 1
    • 2
  • Sh. A. Nasybullin
    • 1
    • 2
  • A. L. Buchachenko
    • 1
    • 2
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow
  2. 2.S. M. Kirov Kazan' Chemicotechnological InstituteUSSR

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