Stereoselectivity of hydrosilylation of olefins

  • A. V. Podol'skii
  • T. G. Cherezova
  • V. P. Kachalkov
  • M. I. Kodess
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Conclusions

It was discovered that disubstituted olefins, in which the double bond is conjugated with an aromatic system, exhibit stereoselective hydrosilylation: only the trans isomers react directly. The hydrosilylation of the cis isomers is accomplished via prior conversion to the trans isomers. It was postulated that the stereoselectivity of the process is based on the trans-addition mechanism.

Keywords

Double Bond Trans Isomer Aromatic System Prior Conversion Disubstituted Olefin 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. V. Podol'skii
    • 1
  • T. G. Cherezova
    • 1
  • V. P. Kachalkov
    • 1
  • M. I. Kodess
    • 1
  1. 1.Institute of ChemistryUral Scientific Center of the Academy of Sciences of the USSRSverdlovsk

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