Conclusions
A method was developed for the thiylation of phenylacetylene with S-alkylisothiuronium salts, which made it possible to obtain cis-β-phenylvinyl alkyl sulfides in high yield, in which connection the stereospecificity of the process is independent of the solvating capacity of the solvent.
Literature cited
W. E. Truce and J. A. Simms, J. Am. Chem. Soc.,78, 2756 (1956).
W. E. Parham, F. D. Blake, and D. R. Theissen, J. Org. Chem.,27, 2415 (1962).
B. A. Trofimov, S. V. Amosova, and V. V. Nosyreva, Zh. Org. Khim.,12, 1366 (1976).
V. I. Laba, A. V. Sviridova, A. A. Kron, and E. N. Prilezhaeva, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1568.
H. J. Schneider, J. J. Bagnell, and G. C. Murdoch, J. Org. Chem.,26, 1980 (1961).
A. N. Volkov, A. N. Kuznetsova, and A. N. Khudyakova, Inventor's Certificate No. 417,418 (1972); Byull. Izobr., No.8, 68 (1974).
H. J. Schneider and J. J. Bagnell, J. Org. Chem.,26, 1984 (1961).
E. P. Gracheva, V. I. Laba, N. K. Kul'bovskaya, and M. F. Shostakovskii, Zh. Obshch. Khim.,33, 2493 (1963).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 213–214, January, 1979.
Rights and permissions
About this article
Cite this article
Kudyakova, R.N., Volkov, A.N. & Trofimov, B.A. Synthesis of β-phenylvinyl alkyl sulfides from isothiuronium salts. Russ Chem Bull 28, 199–200 (1979). https://doi.org/10.1007/BF00925425
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00925425