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Reaction of trialkylsilylalkanethiols with benzenesulfonyl chloride

  • N. N. Vlasova
  • S. A. Bol'shakova
  • Yu. G. Skrypnik
  • E. O. Tsetlina
  • M. G. Voronkov
Brief Communications
  • 23 Downloads

Conclusions

Depending on the ratio of the reactants and the reaction temperature, the reaction of benzenesulfonyl chloride with sodium trialkylsilylalkylthiolates R3Si(CH2)nSNa (R=Me, Et; n=1–3) leads either to labile S-phenyl S′-trialkylsilylalkyl thiosulfonates or to their mixture with S,S′-bis(trialkylsilylalkyl) disulfides.

Keywords

Sodium Chloride Disulfide Reaction Temperature Benzenesulfonyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

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    M. A. Belous and I. Ya. Postovskii, Zh. Obshch. Khim.,20, 1701 (1950).Google Scholar
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    N. N. Vlasova, L. N. Neretina, F. P. Kletsko, E. O. Tsetlina, and M. G. Voronkov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2827.Google Scholar
  3. 3.
    N. N. Vlasova, L. N. Kulikova, E. O. Tsetlina, and M. G. Voronkov, Zh. Obshch. Khim.,44, 2159 (1974).Google Scholar
  4. 4.
    J. L. Kice and E. H. Morkved, J. Am. Chem. Soc.,86, 2270 (1964).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • N. N. Vlasova
    • 1
  • S. A. Bol'shakova
    • 1
  • Yu. G. Skrypnik
    • 1
  • E. O. Tsetlina
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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