Reaction of trialkylsilylalkanethiols with benzenesulfonyl chloride

  • N. N. Vlasova
  • S. A. Bol'shakova
  • Yu. G. Skrypnik
  • E. O. Tsetlina
  • M. G. Voronkov
Brief Communications
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Conclusions

Depending on the ratio of the reactants and the reaction temperature, the reaction of benzenesulfonyl chloride with sodium trialkylsilylalkylthiolates R3Si(CH2)nSNa (R=Me, Et; n=1–3) leads either to labile S-phenyl S′-trialkylsilylalkyl thiosulfonates or to their mixture with S,S′-bis(trialkylsilylalkyl) disulfides.

Keywords

Sodium Chloride Disulfide Reaction Temperature Benzenesulfonyl 

Literature cited

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    N. N. Vlasova, L. N. Neretina, F. P. Kletsko, E. O. Tsetlina, and M. G. Voronkov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2827.Google Scholar
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    N. N. Vlasova, L. N. Kulikova, E. O. Tsetlina, and M. G. Voronkov, Zh. Obshch. Khim.,44, 2159 (1974).Google Scholar
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    J. L. Kice and E. H. Morkved, J. Am. Chem. Soc.,86, 2270 (1964).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • N. N. Vlasova
    • 1
  • S. A. Bol'shakova
    • 1
  • Yu. G. Skrypnik
    • 1
  • E. O. Tsetlina
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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