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Modified steroids. 102. Approach to the synthesis of steroid 16,17-aziridines and stereospecificity of the photoinduced addition of carbethoxynitrene to steroid 16-en-20-ones

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of 16-en-20-keto-steroids with carbethoxynitrene has been studied. The addition of carbethoxynitrene to the Δ16 bond took place exclusively at the α-region of the molecule with the formation of 16α,17α-carbethoxyepimino-20-keto-steroids.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Kamernitskii, Z. I. Istomina, E. P. Serebryakov & A. M. Turuta

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  1. A. V. Kamernitskii
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  2. Z. I. Istomina
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  3. E. P. Serebryakov
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  4. A. M. Turuta
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Additional information

For communication 101, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 186–191, January, 1979.

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Kamernitskii, A.V., Istomina, Z.I., Serebryakov, E.P. et al. Modified steroids. 102. Approach to the synthesis of steroid 16,17-aziridines and stereospecificity of the photoinduced addition of carbethoxynitrene to steroid 16-en-20-ones. Russ Chem Bull 28, 173–178 (1979). https://doi.org/10.1007/BF00925418

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  • DOI: https://doi.org/10.1007/BF00925418

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