Skip to main content
SpringerLink
Log in

Organic derivatives of antimony. IV. Association of alkoxy and chloroalkoxy derivatives of antimony (III) and (V)

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Chlorotetramethoxyantimony was obtained by the action of acetyl chloride on pentamethoxyantimony.

  2. 2.

    Triethoxy-, tripropoxy-, and triisobutoxyantimony are partially associated under conditions of cryoscopy in cyclohexane, while triisopropoxy- and tri-tert-butoxyantimony are monomeric. Under ebullioscopy conditions in CCl4, 2-ethoxy-4-methyl-1, 3,2-dioxastibinane exists in a monomeric form.

  3. 3.

    According to the data of cryoscopic and ebullioscopic measurements, pentaethoxyantimony exists in benzene in a dimeric form. Dimers of tetrachloromethoxy-, trichlorodimethoxy-, and dichlorotrimethoxyantimony are partially dissociated in benzene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. F. Kober, W. Riihl, and L. Zimmer, Ber.,109, 493 (1976).

    Google Scholar 

  2. O. Adler and F. Kober, Z. Anorg. Allg. Chem.,420, 109 (1976).

    Google Scholar 

  3. M. Wieber and N. Baumann, Z. Anorg. Allg. Chem.,402, 43 (1973).

    Google Scholar 

  4. M. Wieber and N. Baumann, Z. Anorg. Allg. Chem.,418, 167 (1975).

    Google Scholar 

  5. N. Baumann and M. Wieber, Z. Anorg. Allg. Chem.,408, 261 (1974).

    Google Scholar 

  6. H. Funk and H. Kohler, J. Prakt. Chem.,12, 322 (1961).

    Google Scholar 

  7. K. Kumar and R. N. Kapoor, J. Chem. UAR,14, 311 (1971).

    Google Scholar 

  8. B. A. Arbuzov, V. S. Vinogradova, R. R. Shagidullin, Yu. M. Mareev, and I. Kh. Shakirov, Izv. Akad. Nauk SSSR, Ser. Khim., 390 (1976).

  9. B. A. Arbuzov, Yu. M. Mareev, and V. S. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 901 (1977).

  10. R. A. Laber and A. Schmidt, Z. Anorg. Allg. Chem.,405, 71 (1974).

    Google Scholar 

  11. A. Meuwsen and U. H. Mögling, Z. Anorg. Allg. Chem.,285, 262 (1956).

    Google Scholar 

  12. R. C. Paul, H. Madan, and S. L. Chadha, J. Inorg. Nucl. Chem.,36, 737 (1974).

    Google Scholar 

  13. B. A. Arbusov, Y. Y. Samitov, Y. M. Mareev, and V. S. Vinogradova, Phosphorus and Sulfur,4, 53 (1978).

    Google Scholar 

  14. H. Preiss, Z. Anorg. Allg. Chem.,380, 65 (1971).

    Google Scholar 

  15. H. Preiss, Z. Anorg. Allg. Chem.,362, 24 (1968).

    Google Scholar 

  16. H. Preiss, Z. Anorg. Allg. Chem.,389, 294 (1972).

    Google Scholar 

  17. A. Maillard and G. Desgrandchamps, C. r. Acad. sci.,A 248, 3571 (1959).

    Google Scholar 

  18. O. D. Dubrovina, Uch. Zap. Kazansk. Univ., Khim.,116, 3 (1956).

    Google Scholar 

  19. D. C. Bradley, B. N. Chakravarti, and W. Wardlaw, J. Chem. Soc., 2381 (A1956).

  20. C. Russias, F. Damm, A. Deluzarche, and A. Maillard, Bull. Soc. Chim. France, 2275 (1966).

  21. H. Meerwein and Th. Bersin, Lieb. Ann. Chem.,476, 138 (1929).

    Google Scholar 

  22. J. J. Ventura, P. H. Ravenscroft, and O. E. Loeffler, German (West) Pat. No. 1950553 (1970); Chem. Abstr.,73, 4810 (1970).

    Google Scholar 

  23. N. K. Vorob'ev, V. A. Gol'tshmidt, and M. K. Karapetyants, Practical Course in Physical Chemistry [in Russian], Goskhimizdat (1952), p. 41.

  24. A. Lehner, Ber.,36, 1105 (1903).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. M. Butlerov Chemical Institute, V. I. Ulyanov-Lenin Kazan' State University, USSR

    B. A. Arbuzov, Yu. M. Mareev & V. S. Vinogradova

Authors
  1. B. A. Arbuzov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. M. Mareev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. S. Vinogradova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 170–173, January, 1979.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arbuzov, B.A., Mareev, Y.M. & Vinogradova, V.S. Organic derivatives of antimony. IV. Association of alkoxy and chloroalkoxy derivatives of antimony (III) and (V). Russ Chem Bull 28, 159–162 (1979). https://doi.org/10.1007/BF00925415

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00925415

Keywords

Search

Navigation