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Synthesis of nitroxyl radicals based on 4-ethynyl-4-hydroxy-2,2,6,6-tetramethylpiperidine

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Stable nitroxyl radical derivatives of 2,2,6,6-tetramethylpiperidine containing functional groups were synthesized: paramagnetic trifluoro-β-diketones, α-hydroxy and α-keto oxides, Mannich bases, tetrahydrofuranones, unsaturated ketones, vinylacetylenic and divinyl monomers, certain diene synthesis adducts, and chelate complexes of Cu(II) and Co(II) with paramagnetic organic ligands.

  2. 2.

    The possibility of the participation of stable nitroxyl radicals in the Mannich, Claisen, Prilezhaev, and Weitz and Scheffer reactions was demonstrated for the first time.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. B. Shapiro, L. N. Skripnichenko, V. V. Pavlikov & É. G. Rozantsev

Authors
  1. A. B. Shapiro
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  2. L. N. Skripnichenko
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  3. V. V. Pavlikov
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  4. É. G. Rozantsev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 151–158, January, 1979.

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Shapiro, A.B., Skripnichenko, L.N., Pavlikov, V.V. et al. Synthesis of nitroxyl radicals based on 4-ethynyl-4-hydroxy-2,2,6,6-tetramethylpiperidine. Russ Chem Bull 28, 140–148 (1979). https://doi.org/10.1007/BF00925412

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  • DOI: https://doi.org/10.1007/BF00925412

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