Skip to main content
SpringerLink
Log in

Catalytic activity of metal complexes anchored to a solid support. 2. Synthesis of palladium complexes on amino-containing silica gels and their properties in the hydrogenation of C=C, C≡C, and C=N bonds

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have prepared palladium complexes anchored to amino-containing silica gels that are active in the hydrogenation of C-C bonds and of the C=N bonds of Schiff bases.

  2. 2.

    In the presence of a palladium complex linked to silica gel containing γ-aminopropyl groups the double bonds hydrogenated stepwise and selectively: cyclopentadiene to cyclopentene, methylcyclopentadiene to methylcyclopentene, dimethylethynylcarbinol to dimethylvinylcarbinol, and Schiff bases to secondary amines.

  3. 3.

    Palladium complexes on supports modified with aminomethyl and tert-aminomethyl groups are unstable and are reduced by hydrogen, liberating palladium metal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. Z. Sharf, V. D. Kopylova, L. P. Karapetyan, E. L. Frumkina, L. Kh. Freidlin, K. M. Saldadze, and V. N. Krutii, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2746.

  2. V. Z. Sharf, L. Kh. Freidlin, V. N. Krutii, A. S. Gurovets, I. B. Slinyakova, L. P.Finn, and V. T. Minakov, Inventor's Certificate No. 598636 (March25, 1978); Byull. Izobr., No. 11 (1978).

  3. V. A. Tertykh and A. A. Chuiko, Teor. Eksp. Khim.,1, 400 (1965).

    Google Scholar 

  4. V. M. Chertov, D. B. Dzhambaeva, and I. E. Neimark, Kolloidn. Zh.,27, 1149 (1965).

    Google Scholar 

  5. I. B. Slinyakova, M. G. Voronkov, and I. E. Krot, Kolloidn. Zh.,35, 480 (1973).

    Google Scholar 

  6. I. B. Slinyakova and L. P. Finn, Zh. Fiz. Khim.,48, 2217 (1974).

    Google Scholar 

  7. L. Horner and H. Ziegler, Liebigs Ann. Chem.,1976, No. 4, 628.

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. Z. Sharf, A. S. Gurovets, L. P. Finn, I. B. Slinyakova, V. N. Krutii & L. Kh. Freidlin

  2. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    V. Z. Sharf, A. S. Gurovets, L. P. Finn, I. B. Slinyakova, V. N. Krutii & L. Kh. Freidlin

Authors
  1. V. Z. Sharf
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Gurovets
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. P. Finn
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. B. Slinyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. N. Krutii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. L. Kh. Freidlin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 104–108, January, 1979.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sharf, V.Z., Gurovets, A.S., Finn, L.P. et al. Catalytic activity of metal complexes anchored to a solid support. 2. Synthesis of palladium complexes on amino-containing silica gels and their properties in the hydrogenation of C=C, C≡C, and C=N bonds. Russ Chem Bull 28, 93–96 (1979). https://doi.org/10.1007/BF00925404

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00925404

Keywords

Search

Navigation