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Hydrogenation of piperylene on Na zeolites

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The activity of the zeolites for the hydrogenation of piperylene decreases in the order NaA ≈ NaM ≫ NaX > NaY ≈ NaE.

  2. 2.

    The selectivity for the hydrogenation of piperylene to n-pentenes on zeolites NaA, NaE, and NaM is not less than 95% with 100% conversion of the original hydrocarbon. In the case of zeolites X and Y the selectivity diminishes with conversion, being ∼80% at ∼60% conversion.

  3. 3.

    The 1-pentene/2-pentene ratio in the reaction products and the formation of a small amount of n-pentane by direct hydrogenation of piperylene without the intermediacy of n-pentenes point to the sequential addition of hydrogen atoms or ions to the piperylene molecule.

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Literature cited

  1. Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and É. É. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 1737.

  2. Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, and M. A. Kapustin, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 1554.

  3. V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, Kh. M. Minachev, and A. A. Goryachev, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 673.

  4. R. A. Karakhanov, V. I. Garanin, V. V. Kharlamov, M. A. Kapustin, B. B. Blinov, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 445.

  5. Kh. M. Minachev, V. V. Kharlamov, V. I. Garanin, and D. B. Tagiev, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 1709.

  6. V. V. Kharlamov and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 280.

  7. V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, and Kh. M. Minachev, Izv. Akad, Nauk SSSR, Ser. Khim.,1975, 2406.

  8. A. A. Vvedenskii, Thermodynamic Calculations of Petrochemical Processes [in Russian], Gostoptekhizdat, Leningrad (1960), p. 315.

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  9. J. E. Germain, Catalytic Conversion of Hydrocarbons, Academic Press (1968).

  10. Proceedings of the Third International Conference on Molecular Sieve Zeolites, Zurich (1973), p. 264.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Kh. M. Minachev, V. V. Kharlamov & N. G. Kharatishvili

Authors
  1. Kh. M. Minachev
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  2. V. V. Kharlamov
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  3. N. G. Kharatishvili
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 97–104, January, 1979.

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Minachev, K.M., Kharlamov, V.V. & Kharatishvili, N.G. Hydrogenation of piperylene on Na zeolites. Russ Chem Bull 28, 86–92 (1979). https://doi.org/10.1007/BF00925403

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  • DOI: https://doi.org/10.1007/BF00925403

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