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The photoelectronic spectra of phosphoryl compounds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The photoelectronic spectra of certain phosphoryl compounds have been obtained and interpreted.

  2. 2.

    It has been shown that the ionization potentials of the pπ,0 orbitals of the phosphoryl oxygen, the enthalpy of hydrogen bond formation, and the bonding energies of the phosphorus 2p electrons are linearly related.

  3. 3.

    Additive substituent increments for the calculation of pπ,0 orbital ionization potentials have been determined.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    V. V. Zverev, Ya. Ya. Villem, V. E. Bel'skii & Yu. P. Kitaev

  2. Tartu State University, USSR

    V. V. Zverev, Ya. Ya. Villem, V. E. Bel'skii & Yu. P. Kitaev

Authors
  1. V. V. Zverev
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  2. Ya. Ya. Villem
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  3. V. E. Bel'skii
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  4. Yu. P. Kitaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 84–89, January, 1979.

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Zverev, V.V., Villem, Y.Y., Bel'skii, V.E. et al. The photoelectronic spectra of phosphoryl compounds. Russ Chem Bull 28, 74–78 (1979). https://doi.org/10.1007/BF00925401

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  • DOI: https://doi.org/10.1007/BF00925401

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