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The photochemisty of aliphatic nitro compounds. 7. The low-temperature flash photolysis of tetranitromethane and its chloro- and fluoro-substituted analogs

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The low-temperature flash photolysis of tetranitromethane, chlorotrinitromethane, and fluorotrinitromethane in DMFA and hydroxyl-containing solutions leads to rupture of the polynitromethane C-N bond with the formation of polynitrocarbanions.

  2. 2.

    Kinetic studies have shown that anion formation in the polynitro-compound photolysis is a first-order process; yields for these reactions have been determined.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    E. M. Maksyutov & V. I. Slovetskii

Authors
  1. E. M. Maksyutov
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  2. V. I. Slovetskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 47–50, January, 1979.

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Maksyutov, E.M., Slovetskii, V.I. The photochemisty of aliphatic nitro compounds. 7. The low-temperature flash photolysis of tetranitromethane and its chloro- and fluoro-substituted analogs. Russ Chem Bull 28, 38–41 (1979). https://doi.org/10.1007/BF00925394

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  • DOI: https://doi.org/10.1007/BF00925394

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