Kinetic study of the reaction of the dioxane complex of dichlorogermylene with benzyl chloride

  • S. P. Kolesnikov
  • B. L. Perl'mutter
  • O. M. Nefedov
Physical Chemistry

Conclusions

  1. 1.

    Kinetic studies of the liquid-phase, reaction of the C4H6O2·GeCl2 complex with benzyl chloride suggest that this reaction proceeds through preliminary dissociation of the complex, followed by penetration of the free dichlorogermylene into the C-Cl bond of the chloride.

     
  2. 2.

    Rate constants and activation parameters for this reaction have been determined at temperatures ranging from 52 to 94°C. The transition state for the penetration step is characterized by a high, negative value of the activation entropy.

     

Keywords

Chloride Entropy Transition State Benzyl Dioxane 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • S. P. Kolesnikov
    • 1
  • B. L. Perl'mutter
    • 1
  • O. M. Nefedov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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