Conclusions
-
1.
It has been shown that there is no correlation between the surface area of the nickel active in the hydrogenation of olefins on nickel-containing zeolites and the surface area determined from the chemisorption of oxygen. This lack of correlation is due to the fact that the reduction of Ni(II) is reversible, the equilibrium point being shifted toward Ni(II) in oxygen, inert gases, and benzene, and toward Ni(0) in olefins.
-
2.
Nickel clusters embedded in the zeolite cavities are incapable of catalyzing the hydrogenation of benzene, the equilibrium point in the reduction of nickel cations being shifted toward the Ni(II) side.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
J. R. Anderson, Structure of Metallic Catalysts, Academic Press, London-New York (1975).
E. Ruckenstein, J. Catal.,26, 70 (1972).
A. A. Slinkin, Structure and Catalytic Properties of Heterogeneous Catalysts, in: Reviews of Science [in Russian], VINITI (1971), p. 51.
D. W. Breck, Zeolite Molecular Sieves: Structure, Chemistry, and Use, Wiley-Interscience (1974).
F. Figueras, H. Gomez, and M. Primet, Adv. Chem. Ser.,121, 480 (1973).
R. A. Dalla Betta and M. Boudart, Fifth International Congress on Catalysis, Academic Press, London-New York (1973), Vol. 2, Preprint 96, p. 1329.
C. Selenina and R. Wencke, Z. Anorg. Allg. Chem.,380, 190 (1972).
W. Romanovski, Z. Anorg. Allg. Chem.,351, 193 (1967).
V. Penchev and Kh. Minchev, Izv. Otd. Khim. Nauki Blg. Akad. Nauk,6, Kn. 2, 403 (1973); V. Penchev, N. Davidova, V. Kanazirev, H. Minchev, and Y. Neinska, Adv. Chem. Ser.,121, 461 (1973).
K. G. Ione, N. N. Bobrov, L. A. Vostrikova, and V. G. Shinkarenko, Soobshch. Kinet. Katral.,1, No. 2, 223 (1974).
Yu. I. Ermakov, B. N. Kuznetsov, L. G. Karakchiev, and S. S. Derbeneva, Kinet, Katal.,14, 709 (1973).
N. E. Buyanova, A. P. Karnaukhov, L. M. Kefeli, I. D. Ratner, and O. N. Chernyavskaya, Kinet. Katal.,8, 868 (1967).
M. S. Borisova, B. N. Kuznetsov, V. A. Dzis'ko, V. I. Kulikov, and S. P. Noskova, Kinet, Ratal.,16, 1028 (1975).
V. A. Dzis'ko, Usp. Khimii,43, 977 (1974).
K. G. Ione, G. M. Beloperkovskii, and G. G. Plachenov, in: Zeolites, Syntheses, Properties, and Applications [in Russian], Nauka (1965), p. 222.
A. A. Davydov, N. N. Bobrov, and Yu. A. Lokhov, Preprint, First All-Union Conference on the Applications of Zeolites in Catalysis [in Russian], Novosibirsk (1976).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 13–19, January, 1979.
Rights and permissions
About this article
Cite this article
Romannikov, V.N., Ione, K.G. & Repina, V.V. The catalytic activity of nickel in type-Y zeolite catalysts for the hydrogenation of unsaturated hydrocarbons. Russ Chem Bull 28, 7–12 (1979). https://doi.org/10.1007/BF00925387
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00925387