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Nuclear quadrupole resonance of cyclic trivalent phosphorus acid chlorides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The35Cl NQR spectra of some cyclic P(III) acid chlorides were studied.

  2. 2.

    An increase in the size of the ring is accompanied by an increase in the35Cl NQR frequencies, independent of the nature of the endocyclic substituents. The addition of mesomeric positive substituents to the phosphorus atom leads to a decrease in the35Cl NQR frequencies and an increase in the length of the P-Cl bond.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    I. A. Nuretdinov, O. N. Nuretdinova, I. A. Safin & D. Ya. Osokin

  2. Kazan Physicotechnical Institute, USSR

    I. A. Nuretdinov, O. N. Nuretdinova, I. A. Safin & D. Ya. Osokin

Authors
  1. I. A. Nuretdinov
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  2. O. N. Nuretdinova
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  3. I. A. Safin
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  4. D. Ya. Osokin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 950–954, April, 1978.

The authors are grateful to R. P. Arshinov for supplying compound (XIV).

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Nuretdinov, I.A., Nuretdinova, O.N., Safin, I.A. et al. Nuclear quadrupole resonance of cyclic trivalent phosphorus acid chlorides. Russ Chem Bull 27, 824–827 (1978). https://doi.org/10.1007/BF00925321

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  • DOI: https://doi.org/10.1007/BF00925321

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