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Nucleophilic addition of sulfenyl chlorides to highly electrophilic fluoroolefins

  • Yu. V. Zeifman
  • L. T. Lantseva
  • I. L. Knunyants
Brief Communications
  • 23 Downloads

Conclusions

  1. 1.

    When catalyzed by chlorine anion or pyridine, alkyl- or arylsulfenyl chlorides add to perfluoroisobutylene or to methyl perfluoromethacrylate by the nucleophilic mechanism.

     
  2. 2.

    Perfluoroisobutylene when reacted with either trichloromethyl- or chlorocarbonylsulfenyl chloride in the presence of chlorine anion adds chlorine at the multiple bond.

     

Keywords

Methyl Chloride Chlorine Pyridine Multiple Bond 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • Yu. V. Zeifman
    • 1
  • L. T. Lantseva
    • 1
  • I. L. Knunyants
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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