Nucleophilic addition of sulfenyl chlorides to highly electrophilic fluoroolefins

  • Yu. V. Zeifman
  • L. T. Lantseva
  • I. L. Knunyants
Brief Communications


  1. 1.

    When catalyzed by chlorine anion or pyridine, alkyl- or arylsulfenyl chlorides add to perfluoroisobutylene or to methyl perfluoromethacrylate by the nucleophilic mechanism.

  2. 2.

    Perfluoroisobutylene when reacted with either trichloromethyl- or chlorocarbonylsulfenyl chloride in the presence of chlorine anion adds chlorine at the multiple bond.



Methyl Chloride Chlorine Pyridine Multiple Bond 
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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • Yu. V. Zeifman
    • 1
  • L. T. Lantseva
    • 1
  • I. L. Knunyants
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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