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Replacement of heteroorganic fragment in heteroorganic derivatives of aliphatic nitro compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The corresponding boric esters of nitronic acids are formed when boron halides are reacted with the trialkylsilyl esters of nitronic acids under mild conditions.

  2. 2.

    The trialkylsuyl esters of nitronic acids are formed by the reaction of the diethylboric esters of nitronic acids with trialkylsilylamines under mild conditions.

  3. 3.

    The boron derivatives of dimethyl nitromalonate (R=H, F or Et in R2B) have the structure of the esters of bis-carbomethoxymethanenitronic acid, in which the boron atom is coordinated with the oxygen group of MeO2C.

  4. 4.

    The diethylboric ester of 2-methyl-2-carbomethoxy-1-propanenitronic acid is a dimer, in which the boron atom is coordinated at the oxygen of N→O.

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Literature cited

  1. M. V. Kashutina, S. L. Ioffe, and V. A. Tartakovskii, Dokl. Akad. Nauk SSSR,218, 109 (1974).

    Google Scholar 

  2. O. P. Shitov, S. L. Ioffe, L. M. Leont'eva, and V. A. Tartakovskii, Zh. Obshch. Khim.,43, 1266 (1973).

    Google Scholar 

  3. O. P. Shitov, L. M. Leont'eva, S. L. Ioffe, B. N. Khasapov, V. M. Novikov, A. U. Stepanyants, and V. A. Tartakoyskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2782.

  4. O. P. Shitov, S. L. Ioffe, L. M. Leont'eva, and V. A. Tartakovskii, Zh. Obshch. Khim.,43, 1127 (1973).

    Google Scholar 

  5. S. L. Ioffe, M. V. Kashutina, V. M. Shitkin, A. Z. Yankevich, A. L. Levin, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 1341.

  6. M. R. Stober, K. W. Michael, and J. L. Speier, J. Org. Chem.,32, 2740 (1967).

    Google Scholar 

  7. R. A. Smiley and W. A. Pritchett, J. Chem. Eng. Data,11, 617 (1966).

    Google Scholar 

  8. J. Klebe, Accounts Chem. Res.,3, 299 (1970).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. L. Ioffe, A. V. Kalinin, T. N. Golovina, B. N. Khasapov & V. A. Tartakovskii

Authors
  1. S. L. Ioffe
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  2. A. V. Kalinin
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  3. T. N. Golovina
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  4. B. N. Khasapov
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  5. V. A. Tartakovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 942–945, April, 1978.

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Ioffe, S.L., Kalinin, A.V., Golovina, T.N. et al. Replacement of heteroorganic fragment in heteroorganic derivatives of aliphatic nitro compounds. Russ Chem Bull 27, 816–819 (1978). https://doi.org/10.1007/BF00925318

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  • DOI: https://doi.org/10.1007/BF00925318

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