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Synthesis of linear polyenoic acids by reaction of sulfones with butadiene, catalyzed by palladium complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A convenient and simple method was developed for obtaining the methyl esters of polyunsaturated carboxylic acids by the cleavage of arylβ-carbomethoxy-β'-mono- and bis-2,7-octadienylmethyl sulfones using either Na/Hg or EtONa.

  2. 2.

    It was shown for the first time that the bis-octadienyl derivatives of arylβ-carbomethoxymethyl sulfones can be obtained from butadiene and arylβ-carbomethoxymethyl sulfones on the catalyst system: Pd (acac)2-(C6H5)3P-(C2H5)Al.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    R. V. Kunakova, G. A. Tolstikov, U. M. Dzhemilev, F. V. Sharipova & D. L. Sazikova

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  1. R. V. Kunakova
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  2. G. A. Tolstikov
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  3. U. M. Dzhemilev
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  4. F. V. Sharipova
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  5. D. L. Sazikova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 931–934, April, 1978.

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Kunakova, R.V., Tolstikov, G.A., Dzhemilev, U.M. et al. Synthesis of linear polyenoic acids by reaction of sulfones with butadiene, catalyzed by palladium complexes. Russ Chem Bull 27, 806–808 (1978). https://doi.org/10.1007/BF00925314

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  • DOI: https://doi.org/10.1007/BF00925314

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