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Asymmetric synthesis in the 1,4-addition of cyclopentadiene to (−)-menthyl methacrylate

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have carried out an asymmetric synthesis of norbornene derivatives by reaction of cyclopentadiene with menthyl methacrylate; at higher temperatures the overall yield of the adduct and the proportion of the exo isomer are much greater, while the optical yield increases slightly.

  2. 2.

    We have calculated the boiling points and Kovats retention indices of the synthetic compounds from the Chromatographie parameters.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    É. G. Mamedov, I. M. Akhmedov, M. M. Guseinov, S. R. Piloyan & E. I. Klabunovskit

  2. Institute of Petrochemical Processes, Sumgait Branch of the Academy of Sciences of the Azerbaidzhan SSR, USSR

    É. G. Mamedov, I. M. Akhmedov, M. M. Guseinov, S. R. Piloyan & E. I. Klabunovskit

Authors
  1. É. G. Mamedov
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  2. I. M. Akhmedov
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  3. M. M. Guseinov
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  4. S. R. Piloyan
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  5. E. I. Klabunovskit
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 883–886, April, 1978.

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Mamedov, É.G., Akhmedov, I.M., Guseinov, M.M. et al. Asymmetric synthesis in the 1,4-addition of cyclopentadiene to (−)-menthyl methacrylate. Russ Chem Bull 27, 764–766 (1978). https://doi.org/10.1007/BF00925302

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  • DOI: https://doi.org/10.1007/BF00925302

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