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Telomerization of ethylene and vinyl chloride with sulfuryl chloride fluoride

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have isolated the products of the radical telomerization of ethylene with FSO2Cl, which contain two monomer units in the chain, and of vinyl chloride with FSO2Cl, which contain one, two, or three monomer units in the chain.

  2. 2.

    Sulfuryl chloride fluoride is a more efficient chain transfer agent than CCl4. Chain transfer to FSO2Cl and the formation of telomers with n=1 by the FSO2CH2ĊH2 and FSO2CH2ĊHCl radicals are inhibited by their high electrophilicity.

  3. 3.

    The Fe(CO)5-DMF system initiates the telomerization of vinyl chloride with FSO2Cl and favors lower telomer homologs.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. A. Grigor'ev, L. S. German & R. Kh. Freidlina

Authors
  1. N. A. Grigor'ev
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  2. L. S. German
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  3. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 865–868, April, 1978.

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Grigor'ev, N.A., German, L.S. & Freidlina, R.K. Telomerization of ethylene and vinyl chloride with sulfuryl chloride fluoride. Russ Chem Bull 27, 747–749 (1978). https://doi.org/10.1007/BF00925297

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  • DOI: https://doi.org/10.1007/BF00925297

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