Conclusions
In the liquid state and in solution, the dichloroanhydride ofα-chloroethylthiophosphonic acid exists as a two-conformer equilibrium with the P=S and C-Cl, and P=S and C-H bonds in trans orientation.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 838–843, April, 1978.
The authors would like to thank A. N. Vereshchagin, R. R. Shagidullin, and N. P. Anoshina for a discussion of certain aspects of this work.
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Raevskii, O.A., Mumzhieva, N.G., Zyablikova, T.A. et al. Geometrical structure of the dighloroanhydride OF α-chloroethylthiophosphonic ACID. Russ Chem Bull 27, 723–727 (1978). https://doi.org/10.1007/BF00925293
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DOI: https://doi.org/10.1007/BF00925293