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Mass spectra of certain derivatives OF 2, 6-di-tert-butyl-p-benzoquinone

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Breakdown of derivatives of 2,6-di-tert-butyl-p-benzoquinone under electron impact proceeds, in part, through tert-butyl group splitting and, in part, through specific reactions of position 4 substituents.

  2. 2.

    2,6-Di-tert-butyl-p-nitrosophenol exists as a quinoid form in the gaseous phase, while the phenylhydrazone of 2,6-di-tert-butyl-p-benzoquinone exists as a tautomer of 3,5-di-tert-butyl-4-hydroxyazo-benzene.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. V. Krokhin, O. S. Chizhov, V. V. Ershov & G. A. Nikiforov

  2. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Krokhin, O. S. Chizhov, V. V. Ershov & G. A. Nikiforov

Authors
  1. A. V. Krokhin
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  2. O. S. Chizhov
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  3. V. V. Ershov
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  4. G. A. Nikiforov
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Additional information

Translated from. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 825–828, April, 1978.

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Krokhin, A.V., Chizhov, O.S., Ershov, V.V. et al. Mass spectra of certain derivatives OF 2, 6-di-tert-butyl-p-benzoquinone. Russ Chem Bull 27, 711–714 (1978). https://doi.org/10.1007/BF00925290

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  • DOI: https://doi.org/10.1007/BF00925290

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