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The effect of DNA on the kinetics of reactions of propyl gallate radicals

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Propyl gallate oxidation in alcoholic NaOH solution has been shown to lead to the formation of radicals.

  2. 2.

    The nature of the radicals formed in this oxidation depends on the NaOH concentration, o-semiquinone ion-radicals being formed in 0.2 M NaOH, and semiquinone ion-radicals, which are subsequently converted into gallic acid radicals, in 2 M NaOH.

  3. 3.

    Addition of DNA reduces the concentrations of the semiquinone ion-radical in 0.2 M NaOH, and promotes the conversion of these radicals into gallic acid radicals in 2 M NaOH.

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Literature cited

  1. N. V. Nikolaeva, K. E. Kruglyakova, N. A. Kiselev, B. K. Vainshtein, and N. M. Émanuél', Dokl. Akad. Nauk SSSR,142, 713 (1962).

    Google Scholar 

  2. V. Ya. Gotlib, I. I. Pelevina, G. G. Afanas'ev, and L. P. Lipchina, Dokl. Akad. Nauk SSSR,192, 6 (1970).

    Google Scholar 

  3. M. T. Nadzhimiddinova, V. A. Sharpatyi, K. E. Kruglyakova, and N. M. Émanuél', Dokl. Akad. Nauk SSSR,182, 1354 (1968).

    Google Scholar 

  4. A. É. Kolmanson, L. P. Lipchina, and A. G. Chetverikov, Biofizika,6, 410 (1961).

    Google Scholar 

  5. M. Adams, M. S. Blois, and R. V. Sands, J. Chem. Phys.,28, 774 (1958).

    Google Scholar 

  6. L. M. Strigun, L. S. Vartanyan, A. S. Volod'kin, A. I. Prokof'ev, and N. M. Émanuél', Izv. Akad. Nauk SSSR, Ser. Khim., 2242 (1968).

  7. L. M. Strigun, A. I. Prokof'ev, F. N. Pirnazarova, and N. M. Émanuél', Izv. Akad. Nauk SSSR, Ser. Khim., 59 (1968).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    N. A. Zakharova, D. L. Lashkova, S. P. Odintsova, G. P. Troitskaya & K. E. Kruglyakova

Authors
  1. N. A. Zakharova
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  2. D. L. Lashkova
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  3. S. P. Odintsova
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  4. G. P. Troitskaya
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  5. K. E. Kruglyakova
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Additional information

Translation from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 813–816, April, 1978.

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Zakharova, N.A., Lashkova, D.L., Odintsova, S.P. et al. The effect of DNA on the kinetics of reactions of propyl gallate radicals. Russ Chem Bull 27, 700–704 (1978). https://doi.org/10.1007/BF00925287

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  • DOI: https://doi.org/10.1007/BF00925287

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