Conclusions
A study has been made of the dehydrogenation of Hantzsch ethers by pyridlne N-oxide. A scheme proposed for this reaction shows the hydride-ion passing over into a complex of the Hantzsch ether with the N-oxide (limiting step), followed by rapid transfer of the H+ ion to the hydride-ion acceptor with elimination of water and the final reaction products.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
Yu. V. Kurbatova, A. S. Kurbatova, O. S. Otroshchenko, A. S. Sadykov, and F. Zairov, Tr. Samar-kandskogo Gos. Univ., No. 206, 138 (1972).
Yu. V. Kurbatova, A. S. Kurbatova, O. S. Otroshchenko, A. S. Sadykov, and V. P. Smiyanova, Tr. Samarkandskogo Gos. Univ., No. 206, 220 (1972).
V. B. Leont'ev, Yu. V. Kurbatova, D. I. Ivnitskii, É. Tuichiev, G. V. Kiereev, O. S. Otroshchenko, and A. S. Sadykov, Tr. Samarkandskogo Gos. Univ., No. 206, 52 (1972).
A. A. Tyshchenko, V. B. Leont'ev, Kh. A. Aslanov, and A. S. Sadykov, Dokl. Akad. Nauk UzSSR, No. 10, 32 (1972).
S. I. Chan and G. P. Kreishman, J. Am. Chem. Soc.,92, 1101 (1970).
Yu. V. Kurbatova, Khim. Rastitel'nykh Veshchestv,4, 103 (1972).
A. S. Kurbatova, Dissertation, Tashkent, 1970.
N. M. Émanuél' and D. G. Knorre, Course in Chemical Kinetics [in Russian], Vysshaya Shkola (1969).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 807–812, April, 1978.
Rights and permissions
About this article
Cite this article
Kireev, G.V., Leont'ev, V.B., Kurbatov, Y.V. et al. Mechanism of the dehydrogenation of the Hantzsch ether with pyridine N-oxide. Russ Chem Bull 27, 696–700 (1978). https://doi.org/10.1007/BF00925286
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00925286