Skip to main content
SpringerLink
Log in

The effect of various types of treatment on the surface layer composition in binary palladium alloys

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reactions of oxidizing and reducing agents can markedly alter the surface compositions in binary alloys of palladium with aluminum, copper, and nickel. The treatment in hydrogen brings about a marked enrichment of the surface of Pd-Cu and Pd-Al alloys with respect to the low-melting metal. Air treatment covers the surface of Pd-Cu and Pd-Ni alloys with copper and nickel oxides.

  2. 2.

    Only catalytic dehydrogenation of cyclohexane to benzene leads to surface enrichment with respect to the second of the components in alloys of palladium with ruthenium and rhodium, redistribution of the metals between body and surface resulting in a sharp increase in the catalytic activity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. M. Gryaznov and V. S. Smirnov, Usp. Khim.,43, 1716 (1974).

    Google Scholar 

  2. R. L. Park, Phys. Today,28, 52 (1975).

    Google Scholar 

  3. Kh. M. Minachev, G. V. Antoshin, and E. S. Shpiro, Probl. Kinet. Katal.,16, 192 (1975).

    Google Scholar 

  4. E. M. Savitskii, V. P. Polyakova, and M. A. Tylkina, Palladium Alloys [in Russian], Nauka (1967).

  5. T. S. Ustinova, E. S. Shpiro, V. S. Smirnov, V. M. Gryaznov, G. V. Antoshin, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 441 (1976).

  6. C. T. H. Stoddart, R. L. Moss, and D. Pope, Surf. Sci.,53, 241 (1975).

    Google Scholar 

  7. K. Wandelt and G. Ertl, Z. Naturforsch.,31, A, 205 (1976).

    Google Scholar 

  8. B. G. Wood and H. Wise, Surf. Sci.,52, 151 (1975).

    Google Scholar 

  9. B. C. Allen, Trans. Met. Soc. AIME,227, 1175 (1963).

    Google Scholar 

  10. S. Engels, J. Hager, and J. Hille, Z. Anorg. Allg. Chem.,406, 45 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    E. S. Shpiro, T. S. Ustinova, V. S. Smirnov, V. M. Gryaznov, G. V. Antoshin & Kh. M. Minachev

  2. A. V. Topchiev Institute of Petrochemical Syntheses, Academy of Sciences of the USSR, Moscow

    E. S. Shpiro, T. S. Ustinova, V. S. Smirnov, V. M. Gryaznov, G. V. Antoshin & Kh. M. Minachev

Authors
  1. E. S. Shpiro
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. S. Ustinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. S. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. M. Gryaznov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. V. Antoshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Kh. M. Minachev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 763–767, April, 1978

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shpiro, E.S., Ustinova, T.S., Smirnov, V.S. et al. The effect of various types of treatment on the surface layer composition in binary palladium alloys. Russ Chem Bull 27, 658–662 (1978). https://doi.org/10.1007/BF00925278

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00925278

Keywords

Search

Navigation