Conclusions
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1.
By the reaction of sulfuric acid with potassium hexafluorotitanate in aqueous solution, the authors have obtained potassium sulfatotetrafluorotitanate as a distinct compound; it has been subjected to x-ray and IR spectroscopic analysis.
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2.
In the compound obtained the sulfato group is coordinated to the central atom in a bidentate manner. Possible structural schemes of this substance are suggested.
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Literature cited
G. P. Luchinskii, Chemistry of Titanium [in Russian], Khimiya (1971).
R. L. Davidovich, M. A. Medkov, and S. B. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., 1222 (1974).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York (1963).
R. L. Davidovich, T. A. Kaidalova, T. F. Levchishina, and V. I. Sergienko, Atlas of Infrared Absorption Spectra and X-Ray Data of Complex Fluorides of Metals of Groups IV and V [in Russian], Nauka (1972).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 752–753, April, 1978.
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Medkov, M.A., Davidovich, R.L. Complex compounds of metals with mixed acido ligands 8. Potassium sulfatofluorotitanate. Russ Chem Bull 27, 648–649 (1978). https://doi.org/10.1007/BF00925275
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DOI: https://doi.org/10.1007/BF00925275