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Reaction of pentafluorobenzoic acid with arylmagnesium bromides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The yield of 2-aryltetrafluorobenzoic acids, formed by the reaction of pentafluorobenzoic acid with Grignard reagents of the o- and p-HC6H4MgBr type, is determined by the position and character of the X substituent.

  2. 2.

    We obtained 3,4-tetrafluorobenzocoumarin from 2-(o-anisyl)tetrafluorobenzoic acid by refluxing with AlCl3 in chlorobenzene.

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Literature cited

  1. T. N. Gerasimova, I. I. Baturina, T. V. Fomenko, V. S. Chertok, V. F. Kollegov, and E. P. Fokin, Zh. Org. Khim.,10, 2166 (1974).

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  2. T. N. Gerasimova, T. V. Fomenko, and E. P. Fokin, Izv. Sibirsk. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,1975, No. 12, Issue 5, 100.

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  5. T. V. Fomenko, T. N. Gerasimova, and E. P. Fokin, Izv. Sibirsk. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,1977, No. 2, Issue 1, 99.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    T. V. Fomenko, T. N. Gerasimova & E. P. Fokin

Authors
  1. T. V. Fomenko
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  2. T. N. Gerasimova
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  3. E. P. Fokin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1880–1883, August, 1977.

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Fomenko, T.V., Gerasimova, T.N. & Fokin, E.P. Reaction of pentafluorobenzoic acid with arylmagnesium bromides. Russ Chem Bull 26, 1742–1745 (1977). https://doi.org/10.1007/BF00925191

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  • DOI: https://doi.org/10.1007/BF00925191

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