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Organoboron compounds. 333. Chelates of boron with β-diimines as ligands and their mass spectra

  • V. A. Dorokhov
  • O. G. Boldyreva
  • B. M. Zolotarev
  • O. S. Chizhov
  • B. M. Mikhailov
Organic Chemistry

Conclusions

  1. 1.

    Dialkylboryl-β-diiminates with an aryl group on the nitrogen atom of the chelate ring were synthesized by the reaction between vinylaminodialkylboranes and nitriles. β-Diiminates with an acetoxy or methoxy group on the boron atom were prepared by nucleophilic substitution at the boron atom.

     
  2. 2.

    In the mass spectra of dialkylboryl-β-diiminates, ions which are formed by loss of an alkyl group from the boron atom give rise to peaks with the greatest intensity.

     

Keywords

Nitrogen Mass Spectrum Boron Nitrile Nitrogen Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • V. A. Dorokhov
    • 1
  • O. G. Boldyreva
    • 1
  • B. M. Zolotarev
    • 1
  • O. S. Chizhov
    • 1
  • B. M. Mikhailov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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