Homolytic addition of dichlorodibromomethane to acrylonitrile and methyl acrylate
- 19 Downloads
The addition of dichlorodibromomethane to acrylonitrile and methyl acrylate initiated by iron pentacarbonyl with a cocatalyst (dimethylaniline, dimethylformamide, iodine) proceeds with the rupture of the C-Br and C-Cl bonds of the addend. Three types of addition products were isolated: BrCCl2CH2CHBrX, BrCCl2CH2CHClX, and Br2CClCH2CHBrX (X=CN, COOCH3).
KeywordsIron Methyl Iodine Acrylate Dimethylformamide
Unable to display preview. Download preview PDF.
- 1.M. S. Kharasch, B. M. Kuderna, and W. Urry, J. Org. Chem.,13, 895 (1948).Google Scholar
- 2.F. K. Velichko, L. V. Vinogradova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 181 (1973).Google Scholar
- 3.N. O. Brace, J. Org. Chem.,32, 2711 (1967).Google Scholar
- 4.M. S. Kharasch, P. S. Skell, and P. Fisher, J. Am. Chem. Soc.,70, 1055 (1948).Google Scholar