Homolytic addition of dichlorodibromomethane to acrylonitrile and methyl acrylate
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The addition of dichlorodibromomethane to acrylonitrile and methyl acrylate initiated by iron pentacarbonyl with a cocatalyst (dimethylaniline, dimethylformamide, iodine) proceeds with the rupture of the C-Br and C-Cl bonds of the addend. Three types of addition products were isolated: BrCCl2CH2CHBrX, BrCCl2CH2CHClX, and Br2CClCH2CHBrX (X=CN, COOCH3).
KeywordsIron Methyl Iodine Acrylate Dimethylformamide
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