Homolytic addition of dichlorodibromomethane to acrylonitrile and methyl acrylate

  • F. K. Velichko
  • L. V. Vinogradova
Organic Chemistry
  • 19 Downloads

Conclusions

The addition of dichlorodibromomethane to acrylonitrile and methyl acrylate initiated by iron pentacarbonyl with a cocatalyst (dimethylaniline, dimethylformamide, iodine) proceeds with the rupture of the C-Br and C-Cl bonds of the addend. Three types of addition products were isolated: BrCCl2CH2CHBrX, BrCCl2CH2CHClX, and Br2CClCH2CHBrX (X=CN, COOCH3).

Keywords

Iron Methyl Iodine Acrylate Dimethylformamide 

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Literature cited

  1. 1.
    M. S. Kharasch, B. M. Kuderna, and W. Urry, J. Org. Chem.,13, 895 (1948).Google Scholar
  2. 2.
    F. K. Velichko, L. V. Vinogradova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 181 (1973).Google Scholar
  3. 3.
    N. O. Brace, J. Org. Chem.,32, 2711 (1967).Google Scholar
  4. 4.
    M. S. Kharasch, P. S. Skell, and P. Fisher, J. Am. Chem. Soc.,70, 1055 (1948).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • F. K. Velichko
    • 1
  • L. V. Vinogradova
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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