Catalytic properties of zeolites in hydrogenation of acetaldehyde and isobutyraldehyde

  • Kh. M. Minachev
  • V. I. Garanin
  • M. A. Kapustin
Organic Chemistry
  • 29 Downloads

Conclusions

Zeolites of various types (A, faujasite, chabazite, erionite, and mordenite with Na, Ca, and Nd cations) are highly active and selective catalysts for the hydrogenation of acetaldehyde and isobutyraldehyde in a 200–350°C interval and an H2 pressure of 30–50 atm, while zeolites NaM and NaA possess the maximum hydrogenating activity.

Keywords

Hydrogenation Acetaldehyde Zeolite Catalytic Property Mordenite 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, and M. A. Kapustin, Izv. Akad. Nauk SSSR, Ser. Khim., 1554 (1974).Google Scholar
  2. 2.
    R. A. Karakhanov, V. I. Garanin, V. V. Kharlamov, M. A. Kapustin, B. B. Blinov, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 445 (1975).Google Scholar
  3. 3.
    F. A. Chernyshkova, D. V. Mushenko, and L. A. Blandina, Neftekhimiya,14, 188 (1974).Google Scholar
  4. 4.
    USA Patent No. 3479143, 10.01.1963; C. A.,72, 25582r (1970).Google Scholar
  5. 5.
    D. Brek, Zeolitic Molecular Networks [in Russian], Mir, Moscow (1976), pp. 37, 445.Google Scholar
  6. 6.
    W. H. Ploder, J. Catal.,23, 358 (1971).Google Scholar
  7. 7.
    M. G. Terekhova, E. N. Eremin, and N. I. Kobozev, Zh. Prikl. Khim.,30, 893 (1957).Google Scholar
  8. 8.
    V. E. Griz, G. S. Gurevich, S. Z. Levin, and P. S. Lyamer, Neftepererab. Neftekhim.,1, 29 (1973).Google Scholar
  9. 9.
    Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, and M. A. Kapustin, Izv. Akad. Nauk SSSR, Ser. Khim., 2673 (1975).Google Scholar
  10. 10.
    Chemist's Reference, Khimiya,1, 362 (1971).Google Scholar
  11. 11.
    T. A. Isakova, Dissertation, Moscow (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • Kh. M. Minachev
    • 1
  • V. I. Garanin
    • 1
  • M. A. Kapustin
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

Personalised recommendations