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Studies in the field of organic metals 3. Nonstoichiometric tetraselenotetracene iodides

  • S. P. Zolotukhin
  • V. F. Kaminskii
  • A. I. Kotov
  • M. L. Khidekel'
  • R. P. Shibaeva
  • É. B. Yagubskii
Physical Chemistry

Conclusions

  1. 1.

    A study has been made of the reactions of tetraselenotetracene with iodine, and measurements have been made on single crystals of the four nonstoichiometric complexes resulting from these reactions.

     
  2. 2.

    It is characteristic that the crystals of these complexes are built up around two independent sublattices, the one for the tetraselenotetracene and the other for the iodine.

     
  3. 3.

    A study of the ESR, electronic, and IR spectra showed that the tetraselenotetracene complexes with iodine are mixed-valence compounds.

     
  4. 4.

    Measurements on individual crystals showed that the conductances of the complexes remained essentially constant over certain well-defined temperature intervals.

     

Keywords

Iodine Iodide Temperature Interval Individual Crystal Organic Metal 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • S. P. Zolotukhin
    • 1
  • V. F. Kaminskii
    • 1
  • A. I. Kotov
    • 1
  • M. L. Khidekel'
    • 1
  • R. P. Shibaeva
    • 1
  • É. B. Yagubskii
    • 1
  1. 1.Chernogolovka Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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